Mechanisms of interaction between metal-organic framework-based material and persulfate in degradation of organic contaminants (OCs): Activation, reactive oxygen generation, conversion, and oxidation

Abstract

Metal-organic frameworks (MOFs)-based materials have been of great public interest in persulfate (PS)-based catalytic oxidation for wastewater purification, because of their excellent performance and selectiveness in organic contaminants (OCs) removal in complex water environments. The formation, fountainhead and reaction mechanism of reactive oxygen species (ROSs) in PS-based catalytic oxidation are crucial for understanding the principles of PS activation and the degradation mechanism of OCs. In the paper, we presented the quantitative structure-activity relationship (QSAR) of MOFs-based materials for PS activation, including the relationship of structure and removal efficiency, active sites and ROSs as well as OCs. In various MOFs-based materials, there are many factors will affect their performances. We discussed how various surface modification projects affected the characteristics of MOFs-based materials used in PS activation. Moreover, we revealed the process of ROSs generation by active sites and the oxidation of OCs by ROSs from the micro level. At the end of this review, we putted forward an outlook on the development trends and faced challenges of MOFs for PS-based catalytic oxidation. Generally, this review aims to clarify the formation mechanisms of ROSs via the active sites on the MOFs and the reaction mechanism between ROSs and OCs, which is helpful for reader to better understand the QSAR in various MOFs/PS systems.