Abstract

Abstract A combination of field emission energy distribution (FEED) and I–V measurements was used to study the field emission mechanisms of tip-shaped molybdenum emitters electrophoretically coated with nominally intrinsic diamond powders. Field-induced band bending was studied as a function of applied voltage and was interpreted in terms of a two-barrier model. Field emitted electrons originated from the conduction band minimum of diamond. Electron injection at the Mo/diamond interface was identified as the dominant field emission current limiting factor. It was concluded that potential negative electron affinity (NEA) properties of diamond did not contribute to a current enhancement. The latter statement was confirmed by the observation that graphite coatings enhanced emission currents in a similar way to diamond coatings.

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