Mechanism of Yttrium composite inclusions on the localized corrosion of pipeline steels in NaCl solution

Abstract

In order to solve the problem of where, why, and how to start pitting, it is necessary to study the influence of different dissolution activity of the internal heterogeneous structures of the complex inclusions. In this paper, mechanism of internal activity difference of two typical Yttrium composite inclusions on pitting corrosion is revealed from atomic scale by using immersion test, FE-SEM/EDS analysis and first-principles calculations. The results show that, for Mg-Y-S composite inclusions, pitting potential is lower than that of the matrix, therefore, The matrix around the composite inclusions dissolves preferentially; for Y-S-O composite inclusions with core-shell structure, Y-O inclusions in the shell are deformed and cracked due to the internal stress of the matrix and Y-S during the immersion process, resulting in the simultaneous dissolution of inclusions and steel matrix.