Abstract
1. The regeneration ofα-naphthylamine (InH) in a secondary alcohol undergoing oxidation (cyclohexanol, isopropanol) occurs as a result of reactions of the radical In with hydroxyperoxide, hydroperoxide, and hydroxyalkyl radicals. The ratio of the rate constants of the reactions: In + radical→InH and In + radical→molecular products is equal to 47 for the hydroxyperoxide radical (75°), 10 for HO2. (75°), and 7 for the hydroxyalkyl radical (120°). 2. Hydroperoxide radicals are formed in alcohols undergoing oxidation according to the reaction of peroxide radicals of the alcohol with hydrogen peroxide. 3. In contrast to hydroxyperoxide radicals, hydroperoxide radicals are not added toα-naphthylamine.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
