Abstract

Abstract New kinetic data from time resolved ONP-data are presented for the solid state photoreaction of a hydrogen transfer from fluorene to photoexcited acridine in doped fluorene single crystals. They remove existing uncertainties about the reaction pathway which proceeds via the lowest excited triplet state of the acceptor. In contrast to general belief, this 3(ππ*) abstraction shows comparable kinetic parameters to 3(nπ*) abstractions observed in solid glass matrix.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call