Abstract
1. The complex studied — penta (dimethylsulfoxido) vanadyl hexathiocyanatoplatinate (I) is an effective catalyst for the low-temperature oxidation of cyclohexene in alcoholic media, ensuring a high reaction rate up to a high degree of conversion. 2. It has been established that there is a synergism between the component parts of the catalyst, the maximum rate of oxidation of cyclohexene being observed with V/Pt=2. 3. In the initial stages of the oxidation of cyclohexene in the presence of (I), the reaction rate is described by the kinetics of a chain growth-chain breaking process.
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More From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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