Abstract
AbstractNickel complexes of cyclam and cyclam derivatives isomerize in aqueous solutions via two different mechanisms: i. deprotonation of one of the coordinated amino groups followed by inversion and ii. cleavage of the Ni–N bond followed by inversion. While the first mechanism is relevant for the di‐ and tri‐valent nickel complexes, the second one occurs for the mono‐valent complexes, and for complexes with tertiary amines as ligands. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
