Abstract
The relationship between the transport properties of various salt forms (H+, Li+, Na+, Cs+) of MF-4SC hybrid membranes containing nanoparticles of crystalline acid zirconium phosphate Zr(HPO4)2 at various relative humidities are investigated with the use of impedance studies and NMR spectroscopy. Modification of the membranes leads to a marked increase in ion mobility, and the maximum effect is observed under reduced humidity conditions. The conductivity of a modified membrane at a relative humidity of 10% is 1.6 × 10−4 Ω−1 cm−1, that is, almost 1.5 orders of magnitude greater than the conductivity of an initial membrane under the same conditions.
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