Abstract
A theoretical study on the Au-catalyzed cycloisomerization of a branched dienyne possessing an acetate at the propargylic position is presented. The peculiar architecture of the dienyne precursor, exhibiting both a 1,6- and a 1,5-enyne skeleton, leads, in the presence of alkynophilic gold catalysts, to a mixture of bicyclic compounds. DFT calculations are presented that rationalize in full THE manifold of reactions that lead to the different products.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
