Abstract
The singlet molecular oxygen-oxidation of tryptophan generates diastereoisomeric dioxindolylalanine (diOia) along with hydroperoxides, alcohols and carbonyl compounds. Mechanistic investigations based on isotopic labeling and MS/MS analyses support diOia formation through a dioxetane intermediate.
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Schedule a callMore From: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology
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