Abstract
The composition of intermediates of the Cp2ZrCl2-catalyzed hydroalumination of α-olefins by isobutylalanes (HAlBui2, AlBui3, ClAlBui2) was studied by dynamic 1H and 13C NMR pectroscopy. The reaction of Cp2ZrCl2 with isobutylalanes affords the complex (Cp2ZrHCl·HAlBui2)2 responsible for α-olefin hydroalumination.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR, Division of chemical science
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