Abstract
Mechanistic probes of a model system for the coenzyme-B12-dependent methylmalonyl–CoA mutase reaction have suggested (i) that the C–Co bond in the alkylcobalamin intermediate is capable of both carbanionic and homolytic cleavage, and (ii) that the skeletal rearrangement most probably takes place at the radical stage.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.