Abstract

The rules for the isotopic exchange of hydrogen with deuterium in toluene under the conditions of its hydrogenation on a nickel-zinc oxide catalyst and the values of the kinetic isotope effects in this reaction, obtained during the replacement of protium by deuterium, indicate a difference in the mechanisms of toluene hydrogenation and isotope exchange, and confirm the hydrogenation scheme that was proposed on the basis of the kinetic data.

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