Abstract
Laser flash photolysis has been used to study the formation of X 2 ·− radical ions (X = Br and Cl) upon photoreduction of IrCl 6 2− complex in methanol solutions, containing free X − ions. It has been shown that two channels of halogen atom formation are possible. These are the reactions Of X − ions with either the primary radical cation CH 3OH ·+ which results from single electron transfer from a methanol molecule to the excited complex or the intermediate, arising from transformation of primary light-excited IrCl 6 2− complex.
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Schedule a callMore From: Journal of Photochemistry & Photobiology, A: Chemistry
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