Abstract
We have investigated the dc and ac conduc- tivities of Se75Te20Sn5 glass from 80 to 290 K in the frequency range 40 to 10 6 Hz. The behavior of the ac conductivity with temperature, T, is similar to that observed in many chalcogenide glasses. In this frequency range the ac conductivity r(x) is proportional to x s . The frequency exponent shows a T dependence. The experi- mental data have been analyzed using the modified bi- polaron correlated barrier hopping model, which assumes that the relaxation time should contain a Meyer-Neldel rule term. It is observed that this model is consistent with temperature dependent dc conductivity, rdc, ac conductiv- ity, rac, and s, for activation energies above 0.1 eV. At high frequency, that is, low activation energy, the behavior changes. We suggest that in this regime, the carriers may tunnel rather than hopping. We also present a correlation between the residual ac prefactor r00(x) and the Meyer- Neldel temperature (TMN), similar to that previously reported for dc conductivity. This similarity points strongly to the dc and ac conduction mechanisms being the same.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.