Mechanism and Performance of Composite Phase Change Materials from the Direct Hydrolysis Residue of Municipal Sludge Loaded with Sodium Acetate Trihydrate.

Abstract

The direct hydrolysis of municipal sludge for the production of oil and gas has become a key research focus, despite the application of hydrolysis residues presenting a challenge. In this study, municipal sludge was directly hydrolyzed in a high-pressure reaction kettle and the hydrolysis residue byproduct was used as a carrier to prepare a composite phase change heat storage material (CPCM), utilizing vacuum impregnation for sodium acetate trihydrate (SAT) loading. The results of Brunauer–Emmett–Teller (BET) and particle size analyses showed that the residue obtained by the hydrolysis of sludge and sawdust with a dry basis ratio of 4:1 had a higher pore volume and a uniform particle size. The adsorption capacity of the hydrolysis residue to SAT reached 600 wt %; the phase change temperature of the CPCM was 56.9 °C, and its latent heat reached 217.9 kJ/kg. The CPCM remained stable during 150 cycles of the melting–solidification process in a water bath and maintained excellent phase change characteristics. The hydrolysis residue can effectively improve the undercooling and phase separation of SAT without other additives.