Mechanism analysis of hydroxypropyl guar gum degradation in fracture flowback fluid by homogeneous sono-Fenton process

Abstract

An effective hybrid system was applied as the first report for the successful treatment of key pollutants (hydroxypropyl guar gum, HPG) in fracturing flowback fluid, and the synergistic index of the hybrid system was 20.45. In this regard, chemical oxygen demand (COD) removal ratio was evaluated with various influencing operating factors including reaction time, H2O2 concentration, Fe2+ concentration, ultrasonic power, initial pH, and temperature. The optimal operating parameters by single-factor analysis method were: the pH of 3.0, the H2O2 concentration of 80mM, the Fe2+ concentration of 5mM, the ultrasonic power of 180W, the ultrasonic frequency of 20-25kHz, the temperature of 39℃, the reaction time of 30min, and the COD removal rate reached 81.15%, which was permissible to discharge surface water sources based on the environmental standards. A possible mechanism for HPG degradation and the generation of reactive species was proposed. Results of quenching tests showed that various impacts of the decomposition rate by addition of scavengers had followed the order of EDTA-2Na<BQ<t-BuOH, therefore OH radicals had a dominant role in destructing the HPG. Based on the kinetic study, it was concluded that Chan Kinetic Model was more appropriate to describe the degradation of HPG. Identification of intermediates by GC-MS showed that a wide range of recalcitrant compounds was removed and/or degraded into small molecular compounds effectively after treatment. Under the optimal conditions, the sono-Fenton system was used to treat the fracturing flowback fluid with the initial COD value of 675.21mg/L, and the COD value decreased to 80.83mg/L after 60min treatment, which was in line with the marine sewage discharge standard. In conclusion, sono-Fenton system can be introduced as a successful advanced treatment process for the efficient remediation of fracture flowback fluid.