Mechanical, structural and oxidation resistance enhancement of carbon foam by in situ grown SiC nanowires

Abstract

A method for processing carbon foams containing both silicon carbide (SiC) nanowires and bulk SiC and silicon nitride (Si3N4) phases has been developed by reaction of powder mixtures containing precursors for carbon, sacrificial template, silicon (Si), short carbon fibers (SCF) and activated carbon (AC). In situ growth of Si nanowires during pyrolysis of the foam at 1000°C under N2 changed the foam׳s microstructure by covering the porous skeleton inside and out. In situ-grown SiC nanowires were found smoothly curved with diameters ranging around two main modes at 30 and 500nm while their lengths were up to several tens of micrometers. SCF were found effectively mixed and well-bonded to pore walls. Following density, porosity and pore size distribution analyses, the heat-treated (HT) foam was densified using a chemical vapor infiltration (CVI) process. Thereafter, density increased from 0.62 to 1.30g/cm3 while flexural strength increased from 29.3 to 49.1MPa. The latter increase was attributed to the densification process as well as to low surface defects, presence of SCF and coating, by SiC nanowires, of the entire SiC matrix porous structure. The foam׳s oxidation resistance improved significantly from 58 to 84wt% residual mass of the heat treated and densified sample. The growth mechanism of Si nanowires was supported by the vapor–liquid–solid mechanism developed under pyrolysis conditions of novolac and reducing environment of coal cover.