Mechanical properties and microstructures of reaction sintered mullite–zirconia composites in the presence of an additive — dysprosia

Abstract

Mullite–zirconia composites were prepared from Indian zircon flour and calcined alumina following the reaction sintering route. Zircon flour and calcined alumina with 0–4.5 mol% dysprosium oxide were attrition milled followed by isostatic pressing and sintering at 1400–1650°C for 2 h. Significant densification was achieved after dysprosia addition as an additive. The thermal expansion coefficient values were found to be reduced in the presence of dysprosia. Dysprosia helps in densification by liquid phase formation as well as by stabilisastion in tetragonal zirconia state. The thermo-mechanical and microstructural characteristics of the composites were discussed.