Mechanical properties and enhancement mechanism of iron ore tailings as aggregate for manufacturing ultra-high performance geopolymer concrete

Abstract

Reusing of iron ore tailings (IOT), particularly as recycled aggregate to prepare concrete, plays an important role in reducing dependence on natural resources and solving the problem of waste accumulation. In this paper, the effects of IOT as aggregate on the flowability, compressive strength of ultra-high performance geopolymer concrete (UHPGC) were studied, and the enhancement mechanism of IOT on compressive strength was elucidated through microscopic characterizations. The results show that with the increase of IOT content, the flowability of UHPGC decreases, and the compressive strength increases first and then decreases. 25 % IOT replacement yielded the best compressive strength, and 50 % substitution of IOT was comparable to the without IOT regarding compressive strength. The microstructure analysis shows that the crystalline components in the IOT do not participate in the hydration reaction and have the effect of micro-aggregate filling. The amorphous components on the IOT dissolve rapidly in the early stage, participate in geological polymerization reaction, and produce synergistic effect with slag to promote the formation of hydration products. However, excessive IOT incorporation will inhibit the dissolution of slag active ions and hinder the formation of hydration products. In addition, the enhanced interfacial transition zone (ITZ) and mechanical interlocking effect formed by IOT can effectively inhibit the crack development of UHPGC.