Mechanical performance and water resistance of biochar admixture lightweight magnesium oxychloride cement

Abstract

The applications of magnesium oxychloride cement (MOC) have been extensively studied recently due to its eco-friendly and high-strength nature. However, one of the significant limitations of MOC is its poor water resistance. To address this limitation, this study explored the prospect of incorporating biochar particles (up to 25 % of the dry mass of MgO) to form lightweight MOC with improved water resistance. The compressive (fc) and flexural (ff) strengths were investigated after 28-day curing and under 56-day water attack. The fc of MOC after immersion was determined under both wet (directly after immersion) and dry (air-dried to constant weights) conditions. The results indicated that the inclusion of 5 % and 10 % biochar increased the 28-day fc, while the addition of biochar decreased ff regardless of its dosage. Microscopic examination uncovered that the increase in strength resulted from the promoted production of phase 5 (5 Mg(OH)2·MgCl2·8H2O) and the reduction in unreacted MgO. The inclusion of 5 % and 10 % biochar increased the compressive and flexural strength retention ratios after 56-day immersion. The ff with 5 % biochar inclusion after immersion was higher compared to that of pure MOC. Moreover, the inclusion of biochar had minimal effects on the thermal degradation of MOC. The above results suggest that biochar can be a potential additive to enhance the mechanical behaviour and water resistance of MOC. As fc of immersed MOC increased during air-drying, a new equation was developed to describe variations in fc of MOC subject to different degrees of saturation during drying.