Mechanical Behaviors of Microalloyed TRIP-Assisted Annealed Martensitic Steels under Hydrogen Charging.

Xiongfei Yang,Chenghao Song,Lili Li,Hao Yu

doi:10.3390/ma14247752

Abstract

Transformation Induced Plasticity (TRIP)-assisted annealed martensitic (TAM) steel sheets with various microalloying additions such as niobium, vanadium, or titanium were prepared on laboratory scale and subjected to a double-quenching and austempering heat treatment cycle. Slow strain rate tensile (SSRT) was tested on the investigated TAM steels with and without hydrogen charging to reveal their tensile behaviors and hydrogen induced embrittlement effects. Microstructure observations by scanning electron microscope (SEM) are composed of a principal annealed martensitic matrix and 11.0–13.0% volume fraction of retained austenite, depending on the type of microalloying addition in the different steels. SSRT results show that these TRIP-assisted annealed martensitic steels under air media conditions combine high tensile strength (>1000 MPa) and good ductility (~25%), while under hydrogen charging condition, both tensile strength and ductility decrease where tensile strength ranges between 680 and 760 MPa, down from 1000–1100 MPa, and ductility loss ratio is between 78.8% and 91.1%, along with a total elongation of less than 5%. Hydrogen charged into steel matrix leads to the appearance of cleavage fractures, implying the occurrence of hydrogen induced embrittlement effect in TAM steels. Thermal hydrogen desorption results show that there are double-peak hydrogen desorption temperature ranges for these microalloyed steels, where the first peak corresponds to a high-density dislocation trapping effect, and the second peak corresponds to a hydrogen trapping effect exerted by microalloying precipitates. Thermal desorption analysis (TDS) in combination with SSRT results demonstrate that microalloying precipitates act as irreversible traps to fix hydrogen and, thus, retard diffusive hydrogen motion towards defects, such as grain boundaries and dislocations in microstructure matrix, and eventually reduce the hydrogen induced embrittlement tendency.

Highlights

Advanced high strength steels (AHSSs), due to their high performance and capability of satisfying with increasing environmental-friendly requirements, have seen extensive application in various fields such as engineering, machinery, and automobiles [1,2]
The thermal hydrogen desorption rate vs heating temperature during the process of heating up to 800 ◦C for the four hydrogen-charged steels is plotted in Figure 6, where the incorporated chart is the enlarged second-peak section shown in the corresponding chart
TAM steels with various kinds of microalloying additions were prepared by a specially designed double-quenching and austempering heat treatment cycle

Summary

Introduction

Advanced high strength steels (AHSSs), due to their high performance and capability of satisfying with increasing environmental-friendly requirements, have seen extensive application in various fields such as engineering, machinery, and automobiles [1,2]. Previous works [4,5,6,7,8,9,10] showed that after the introduction of various kinds of hydrogen traps into a steel matrix, the hydrogen induced delayed fracture behavior in high strength steels could be alleviated. For example, structure defects like grain boundary and dislocation, retained austenite, MnS inclusion, and microalloying precipitates such as NbC, TiC, and NbN, have been intensively investigated. They are classified into reversible or irreversible traps depending on their ability to absorb hydrogen, as indexed by activation energy [4,5,6,7]

Methods

Results

Conclusion