Abstract

In this paper, multiwalled carbon nanotubes (MWCNTs) were synthesized by spray pyrolysis to be used later as material reinforcement in the production of MWCNTs/Al7075 aluminum composites. Both, MWCNTs and MWCNTs/Al7075 composites were microstructurally and mechanically characterized. Scanning electron microscopy (SEM) analysis shows MWCNTs formed by multiple layers rolled on themselves forming a tube shape with lengths up to 1300 µm and diameters ranging from 55 to 120 nm. MWCNTs were added to the aluminum matrix in different concentrations up to 3.0 wt%. Their dispersion in the aluminum matrix was carried out by ultrasonic/methanol method followed by high-energy mechanical milling process. The effect of MWCNTs on the morphology and mechanical behavior of composites were evaluated. Results indicate that a homogeneous dispersion of CNTs was obtained as a consequence of the dispersion routes used in the production of composites, observing no damage on their morphology. The mechanical behavior of the composites shows a noticeable improvement for MWCNTs concentrations above 2.0 wt%, with ductility similar to that found in the literature for the Al7075 commercial alloy.

Highlights

  • The most important methods developed to produce single and multiwalled carbon nanotubes include electric arc discharge, laser ablation and catalyzed chemical vapor deposition (CCVD)1

  • The conditions used in this experimentation were the adequate for successfully synthesize multiwalled carbon nanotubes (MWCNTs) by the spray pyrolysis method

  • The MWCNTs having multiwalled hollow structures possess few impurities, such as amorphous carbon shown in Figure 4b 24; this suggests that the purity of MWCNTs is sufficient for them to act as good reinforcing material in the following treatment without further purification 25

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Summary

Introduction

The most important methods developed to produce single and multiwalled carbon nanotubes include electric arc discharge, laser ablation and catalyzed chemical vapor deposition (CCVD). CCVD has been reported to be a lowcost method in producing multiwalled carbon nanotubes (MWCNTs) and nanotube bundles. Spray pyrolysis is a type of CCVD method in which it is possible to produce large amounts of well graphitized, multiwalled carbon nanotubes at low cost, with the promise of industrial up-scaling 2. Carbon nanotubes (CNTs) have emerged as an important class of new materials for structural engineering and functional applications due to their high mechanical strength, electrical and thermal conductivities 6-8. Their high aspect ratio and intrinsic properties make CNTs the most effective reinforcement to produce composite materials.

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