Abstract

The magnetic tuning of the low rotational levels in the (v=0) X2Σ+, (v=0) A2Π, and (v=0) B2Σ+ electronic states of calcium monofluoride, CaF, have been experimentally investigated using high resolution optical Zeeman spectroscopy of a cold molecular beam. The observed Zeeman shifts and splittings are successfully modeled using a traditional effective Hamiltonian approach to account for the interaction between the (v=0) A2Π and (v=0) B2Σ+ states. The determined magnetic g-factors for the X2Σ+, B2Σ+ and A2Π states are compared to those predicted by perturbation theory.

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