Abstract
The light scattering properties of seawater play important roles in radiative transfer in the ocean and optically-based methods for characterizing marine suspended particles from in situ and remote sensing measurements. The recently commercialized LISST-VSF instrument is capable of providing in situ or laboratory measurements of the volume scattering function, β p ( ψ ) , and the degree of linear polarization, DoLP p ( ψ ) , associated with particle scattering. These optical quantities of natural particle assemblages have not been measured routinely in past studies. To fully realize the potential of LISST-VSF measurements, we evaluated instrument performance, and developed calibration correction functions from laboratory measurements and Mie scattering calculations for standard polystyrene beads suspended in water. The correction functions were validated with independent measurements. The improved LISST-VSF protocol was applied to measurements of β p ( ψ ) and DoLP p ( ψ ) taken on 17 natural seawater samples from coastal and offshore marine environments characterized by contrasting assemblages of suspended particles. Both β p ( ψ ) and DoLP p ( ψ ) exhibited significant variations related to a broad range of composition and size distribution of particulate assemblages. For example, negative relational trends were observed between the particulate backscattering ratio derived from β p ( ψ ) and increasing proportions of organic particles or phytoplankton in the particulate assemblage. Our results also suggest a potential trend between the maximum values of DoLP p ( ψ ) and particle size metrics, such that a decrease in the maximum DoLP p ( ψ ) tends to be associated with particulate assemblages exhibiting a higher proportion of large-sized particles. Such results have the potential to advance optically-based applications that rely on an understanding of relationships between light scattering and particle properties of natural particulate assemblages.
Highlights
It has long been recognized that inherent light-scattering properties of natural waters are of crucial importance and have strong potential for wide-ranging applications in aquatic sciences, including oceanography
The comparison of measurements with such reference values allows for evaluation of performance of LISST-VSF instrument and formulation of calibration correction functions for improved determinations of the volume scattering function and the degree of linear polarization from this instrument
The evaluation results presented in this study are relevant to the specific version of the LISST-VSF instrument used in our laboratory, most methodological aspects are generally applicable to evaluation of other light scattering instruments
Summary
It has long been recognized that inherent light-scattering properties of natural waters are of crucial importance and have strong potential for wide-ranging applications in aquatic sciences, including oceanography. These properties are essential inputs to the radiative transfer models used to compute the ambient light fields in natural water bodies [1,2,3,4]. Despite the potential usefulness of information provided by light scattering measurements, the complexity and variability in composition of natural particulate assemblages impose significant challenges in achieving an understanding of bulk light-scattering properties of seawater in terms of detailed compositional characteristics of particulate matter [35]
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