Abstract

Superconducting Nb <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</inf> Sn Cavities have potential advantages over rf cavities with Nb surfaces To test possible applications and to improve the understanding of Nb <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</inf> Sn coatings on Nb, rf cavities have been measured between 1.5 and 8K and between 0.1 and 7GHz. The temperature dependence of the surface resistance R(T) indicates weak superconducting spots with transition temperatures <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">T\min{c}\max{\ast} &lt; 1</tex> K and <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">T\min{c}\max{\ast} \simeq 2.5</tex> K. The normal conducting spots <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">T\min{c}\max{\ast} \lsim 1</tex> K cause the large rf residual losses <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">R'_{res} \propto f^{2}</tex> observed up to date. The spots with <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">T\min_{c}\max_{\ast} \simeq 2.5</tex> K cause temperature dependences of <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">R'(T)</tex> between 2 and 6K, where R <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">BCS</inf> (Nb <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</inf> Sn) is still negligible. In line with <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">R_{res} \propto f^{2}</tex> , the lowest rf losses <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">R_{res} &lt; 2.10^{-9}\Omega</tex> and the highest field strength <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">B_{crit} = 83 m^{T}(\wedgeE_{peak} = 29&lt;/texMV/m)</tex> have been observed at the lowest frequency 0.1GHz measured. Surface resistance and penetration depth measurements have shown that grain boundaries or hydrogen clusters do not cause the weak spots observed with <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">T\min{c}\max{\ast} &lt; 2.5</tex> K. The origin and the chemistry of the weak spots with <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">T\min{c}\max{\ast} \lsim 1</tex> K, which cause the large <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">R_{res} \propto f^{2}</tex> and the low <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">B_{crit} (T) \simeq const</tex> , are still not clear. They seem related to the Nb <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</inf> Sn surface. The weak spots with <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">T\min{c}\max{\ast} \simeq 2.5</tex> K consist most likely of Nb <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</inf> Sn <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">5</inf> , which in cooling below 950°C precipitates due to the excess Sn present in Nb <inf xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</inf> Sn coatings grown in Sn vapor.

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