Abstract
Raman and infrared spectroscopic studies have been performed on aqueous calcium and magnesium nitrite solutions over a wide range of solution compositions. Stability constants have been calculated from quantitative intensity measurement of bands in the v2 nitrite region arising from free and complexed nitrite. The measured values at 25°C. are: Ca(NO2)2, β1 = 0.18 at ionic strength 5.8; Mg(NO2)2, β1 = 0.061 at ionic strength 8.2. The populations of calcium nitrite complexes were found to increase considerably with increased ionic strenth, but complex formation was not temperature-sensitive in either case. Differences in relative intensities, between infrared and Raman spectra are discussed.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
