Measurement of the rheological properties of polymer melts with annular rheometer

Abstract

An annular die has been designed having a very thin gap distance between two coaxial cylinders. The die was then used to measure wall normal stresses along the longitudinal direction of polymer melts flowing through the thin annulus. The materials investigated were high-density polyethylene, low-density polyethylene, polypropylene, and polystyrene. Also investigated were blends of polystyrene and polypropylene, and blends of polystyrene and high-density polyethylene The measurements of wall normal stresses were used to determine the rheological properties of the melts, namely, the melt viscosity from the slope of axial wall normal stress profiles and the melt elasticity from exit pressures. The interpretation of the experimental data was made possible by the fact that the narrow-gap annular die can be considered as a substitute for a thin slit die. It has been found that the results obtained in the present study are consistent with those reported earlier by the author, who at that time used both capillary and slit dies.