Abstract
AbstractThe proper condensation temperatures of nanosilica powder modified by silane coupling agents such as 3‐methacryloxypropyl trimethoxy silane (MEMO), [3‐(2‐aminoethyl)aminopropyl] trimethoxy silane (AMMO), and bis[3‐(triethoxysilyl)propyl] disulfide (TESPD) were measured with Fourier transform infrared. Moreover, the structure and properties of solution‐polymerized styrene–butadiene rubber (SSBR) filled with nanosilica powder that was organically modified by the three silane coupling agents at different temperatures were investigated. The results showed that the proper condensation temperatures of nanosilica powder modified by MEMO, AMMO, and TESPD were about 80, 80, and 100°C, respectively. Compared with SSBR filled with silica powder, SSBR filled with silica powder modified by a silane coupling agent exhibited not only better filler‐dispersion and mechanical properties but also lower internal friction loss in a selected range of strains. Furthermore, when the organic modification was carried out at the proper condensation temperature, the improvement of the modification effect became more obvious. Among these silane coupling agents, AMMO presented the most remarkable modification effect for nanosilica. The mechanism of modification for silica powder and its enhancement of the properties of SSBR were examined. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008
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