Measurement of nitrogen depth profile in steel

Abstract

The characterization of nitridated steel samples, in special the depth profile of nitrogen, aims to help improving the quality of the surface and to increase the durability of the steel pieces. In this work we used ERDA and NRA to determinate the profile of nitrogen in different sets of stainless steel samples. An incident beam of 35Cl of 56MeV was used for ERDA analysis of a first set of samples. Results indicated an homogeneous distribution for most of the identified elements, with atomic nitrogen concentrations around 2% in the analyzed depth range (0.2μm) and the presence of thin films on the surface (about 50×1015at/cm2), one of C and the other of iron oxide. In a second set of samples, 4.43MeV gamma rays produced from 15N(H,αγ)12C reaction, using an external proton beam of 1.3 MeV, were used to quantify nitrogen concentration. N concentrations of about 0.47% were obtained comparing the gamma production rate of the samples with a referenced material (Stainless steel CRM298 – 0.236% of N in mass) irradiated in the same conditions. Also PIXE analyses were done on both sets of samples in order to identify main elements in the matrix.