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Abstract
New data have been determined by differential ebulliometry for limiting activity coefficients of binary systems of water. Results are reported with acetone, N,N-dimethylformamide, ethyl acetate, isopropanol, methanol, nitromethane and tetrahydrofuran over a modest range of temperatures. The results are used to demonstrate the limitations of several current excess GibbS energy expressions in representing both vapour—liquid equilibrium and liqui—liquid equilibrium data from limiting activity coefficient measurements.
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