Abstract

Several points have been investigated which are of technological interest regarding cells involving zirconia-yttria solid solutions. The use of a metallic band coated on the electrolyte as a current lead to an electrode induces errors in the measurement of oxygen partial pressures due to local thermoelectric effects. The time dependences of platinum and silver electrodes have been measured as functions of oxygen partial pressure and temperature. A discontinuous use of gauges for analysing CO-CO2 samples which gives the composition with an accuracy of 4% is described.

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