Abstract
The solubility of C 14, C 16 n-alkanols (1-tetradecanol and 1-hexadecanol) in hexadecane and 1-tetradecanol in heptane has been measured by a dynamic method from 290 K to the melting point. These and previous data concerning solubilities in normal alkanes ( C 7 C 15) are correlated by means of Wilson, UNIQUAC, UNIQUAC ASM and two modified NRTL equations. The root-mean-square deviations of the solubility temperatures for all calculated data vary from 0.1 to 3.2 K and depend on the particular equation used. In the calculations, the existence of two solid-solid first-order phase transitions in alkanols has also been taken into consideration.
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