Abstract
The solubility of carbon dioxide in the ionic liquids 1-butyl-3-methylimidazolium hexafluorophosphate and 1-nonyl-3-methylimidazolium hexafluorophosphate was measured at temperatures of 293.15 and 298.15 K and pressure up to 4 MPa using a stoichiometric phase equilibrium apparatus. The measured data for 1-butyl-3-methylimidazolium hexafluorophosphate were in good agreement with existing literature data and new solubility data were reported for 1-nonyl-3-methylimidazolium hexafluorophosphate. The measured data were correlated using the group contribution non-random lattice fluid equation of state (GC-NLF EoS) proposed by Lee and co-workers. The group parameters for CG-NLF EoS were slightly modified at limited range to accommodate recent experimental data and better prediction at high pressure and long alkyl chains.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.