Abstract
Sulfolane is an important aprotic polar solvent. Liquid-liquid equilibrium (LLE) data for the ternary systems of water + 1,2-dichloroethane + sulfolane were measured at temperatures of 288.15, 298.15 and 308.15 K under the atmospheric pressure. The distribution coefficient and selectivity were determined from the measured LLE data, which showed that 1,2-dichloroethane is a suitable extractant for the recovery of sulfolane from its aqueous solution. The nonrandom two-liquid (NRTL) model and the universal quasi-chemical (UNIQUAC) model were utilized to correlate the experimental LLE data. The low values of RMSD indicated that the ternary system could be fitted well by the NRTL and UNIQUAC models. The consistency of the binary interaction parameters for the two thermodynamic models obtained was confirmed by the topological information contained in the Gibbs energy of mixing function ( G M / RT ).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
