Abstract
The mean amplitudes of vibration for twelve phosphine—boranes, X 3P·BY 3 (X = H, D, F; Y = H, D, F, Cl, Br, I), have been calculated on the basis of structural and spectroscopic data from the literature. Potential barriers to internal rotation have also been determined from torsional frequencies and from calculated mean-square amplitudes of vibration. Results obtained using Pitzer's and Karle's methods of barrier height calculation are compared.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
