Abstract
Schrock carbene complex Mo( CHCMe 2Ph)( N-2,6- i-Pr 2C 6H 3)[OCMe(CF 3) 2] 2 was immobilized on mesoporous molecular sieves MCM-41 via a ligand exchange reaction with OH surface groups. The heterogeneous catalyst prepared in this way was Mo-leaching resistant and exhibited high activity and selectivity in metathesis of neat 1-heptene. The catalyst activity in cross-metathesis of 1-heptene with norbornene and cyclooctene was also studied.
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