Maximum substitution of magnesium for calcium sites in Mg-β-TCP structure determined by X-ray powder diffraction with the Rietveld refinement

Abstract

The purpose of this study was to determine the maximum substitution of magnesium, Mg 2+, for calcium, Ca 2+ sites in a beta-tricalcium phosphate (Mg-β-TCP) powder using the Rietveld method. Ca-deficient apatite with a theoretical 0.2 Mg/Ca ratio was synthesized and the resultant powder sintered at 1000 °C for 4 h. The maximum Mg 2+ substitution of nearly 15 mol% in β-TCP structure was deduced from the occupancy factors. The analysis indicated that the maximum substitution of Mg 2+ on the M(4) and M(5) sites was, approximately, 4.21 and 10.72 mol%, corresponding to the Ca 2.61(Mg1 0.28,Mg2 0.11)(PO 4) 2 stoichiometric formula. A small displacement of the Ca atoms position was observed around the Mg1(5)PO 4 octahedral, and their increasing shift to the PO 4 triangles corners.