Abstract
Laser-ablated group 6 transition metal atoms react with BF3 to yield typical transition metal inserted complexes F2B-MF (M = Cr, Mo, and W) and terminal borylene complex FB[triple bond, length as m-dash]WF2. These products are investigated by using infrared spectroscopy, isotopic substitution and theoretical frequency calculations. The inserted complexes F2B-MF (M = Cr, Mo, and W) were identified by antisymmetric and symmetric stretching modes of F-B-F. The FB[triple bond, length as m-dash]WF2 molecule has a 11B-F (10B-F) stretching frequency at 1453.2 (1505.0) cm-1 and the triple bond between boron and tungsten is confirmed by EDA-NOCV calculations, CASSCF calculation and NBO analysis. Furthermore, the bonding for tungsten complexes is compared with that of molybdenum and chromium complexes, which reveals interesting differences in their chemistries.
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