Matrix infrared spectra of HF complexes with N 2O, OCS and CS 2

Abstract

Solid neon/N 2O/HF mixtures reveal infrared spectra of the N 2O---HF and ON 2---HF structural isomers of the hydrogen bonded complexes observed in nozzle beam expansions. Solid argon/OCS/HF and argon/CS 2/HF mixtures yield spectra of the SCO---HF and CS 2---HF complexes and provide several interesting comparisons with CO 2---HF complex spectra.