Abstract

Nitrogen and proton coupling tensors have been measured for the [Formula: see text] radical trapped in five different single crystal matrices. As all isotropic coupling constants are the same within experimental error (aN = 21.2 G, aH = 28.4 G), no measurable crystal field effect is found. In these solids the motions of the radical depend on the dimension of the trapping cage and the motions of the surrounding molecules.

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