Abstract

We present a model of the molecular transistor, operation of which is based on the interplay between two physical mechanisms, peculiar to open quantum systems that act in concert: {mathscr{P}}{mathscr{T}} -symmetry breaking corresponding to coalescence of resonances at the exceptional point of the molecule, connected to the leads, and Fano-Feshbach antiresonance. This switching mechanism can be realised in particular in a special class of molecules with degenerate energy levels, e.g. diradicals, which possess mirror symmetry. At zero gate voltage infinitesimally small interaction of the molecule with the leads breaks the {mathscr{P}}{mathscr{T}} -symmetry of the system that, however, can be restored by application of the gate voltage preserving the mirror symmetry. {mathscr{P}}{mathscr{T}} -symmetry broken state at zero gate voltage with minimal transmission corresponds to the “off” state while the {mathscr{P}}{mathscr{T}} -symmetric state at non-zero gate voltage with maximum transmission – to the “on” state. At zero gate voltage energy of the antiresonance coincides with exceptional point. We construct a model of an all-electrical molecular switch based on such transistors acting as a conventional CMOS inverter and show that essentially lower power consumption and switching energy can be achieved, compared to the CMOS analogues.

Highlights

  • We present a model of the molecular transistor, operation of which is based on the interplay between two physical mechanisms, peculiar to open quantum systems that act in concert: PT -symmetry breaking corresponding to coalescence of resonances at the exceptional point of the molecule, connected to the leads, and Fano-Feshbach antiresonance

  • Coupling of spatially symmetric molecule to electrodes results in PT -symmetry breaking, which is accompanied by coalescence of resonances[29] at the exceptional point of an open quantum system comprised of the molecule and the electrodes[28,30] and transmission decrease

  • An open quantum system should be spatially symmetric in order to possess EP

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Summary

Introduction

We present a model of the molecular transistor, operation of which is based on the interplay between two physical mechanisms, peculiar to open quantum systems that act in concert: PT -symmetry breaking corresponding to coalescence of resonances at the exceptional point of the molecule, connected to the leads, and Fano-Feshbach antiresonance. This switching mechanism can be realised in particular in a special class of molecules with degenerate energy levels, e.g. diradicals, which possess mirror symmetry. The mentioned special class of molecules consists of systems with degenerate energy levels, e.g. diradicals[31,32,33] (but not restricted to), which possess mirror symmetry

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