Abstract

The paper presents results of mathematical modelling of HClO 4 radiolysis. Using experimental yields of ClO 2, ClO 3 −, Cl − and comparing them with calculated values the yields of ClO 2 and ClO 3 − formed by the mechanism of the direct action of radiation on ClO 4 − ions and the values of rate constants of reactions ClO 2 + OH, ClO 2 + HO 2, ClO 2 − + HO 2, ClO + H 2O 2, Cl + H 2O 2 were found.

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