Materials for Low‐Temperature Fuel Cells

Abstract

KEY MATERIALS FOR LOW-TEMPERATURE FUEL CELLS: AN INTRODUCTION ALKALINE ANION EXCHANGE MEMBRANE FUEL CELLS Fuel Cells PEM Fuel Cell Principles Alkaline Fuel Cells Summary CATALYST SUPPORT MATERIALS FOR PROTON EXCHANGE MEMBRANE FUEL CELLS Introduction Current Status of Support Materials and Role of Carbon as Support in Fuel Cells Novel Carbon Materials as Electrocatalyst Support for Fuel Cells Conductive Metal Oxide as Support Materials Metal Carbides and Metal Nitrides as Catalyst Supports Conducting Polymer as Support Materials for Fuel Cells Conducting Polymer-Grafted Carbon Materials 3M Nanostructured Thin Film as Support Materials for Fuel Cells Summary and Outlook ANODE CATALYSTS FOR LOW-TEMPERATURE DIRECT ALCOHOL FUEL CELLS Introduction Anode Catalysts for Direct Methanol Fuel Cells: Improved Performance of Binary and Ternary Catalysts Anode Catalysts for Direct Ethanol Fuel Cells: Break C-C Bond to Achieve Complete 12-Electron-Transfer Oxidation Anode Catalysts for Direct Polyol Fuel Cells (Ethylene Glycol, Glycerol): Cogenerate Electricity and Valuable Chemicals Based on Anion Exchange Membrane Platform Synthetic Methods of Metal Electrocatalysts Carbon Nanomaterials as Anode Catalyst Support Future Challenges and Opportunities MEMBRANES FOR DIRECT METHANOL FUEL CELLS Introduction Basic Principles of Direct Methanol Fuel Cell Operation Membranes for Direct Methanol Fuel Cells Membrane Properties Summary Conclusions HYDROXIDE EXCHANGE MEMBRANES AND IONOMERS Introduction Requirements Fabrications and Categories Structure and Properties of Cationic Functional Group Structure and Properties of Polymer Main Chain Structure and Properties of Chemical Cross-Linking Prospective MATERIALS FOR MICROBIAL FUEL CELLS Introduction MFC Configuration Anode Materials Cathode Separators Outlook BIOELECTROCHEMICAL SYSTEMS Bioelectrochemical Systems and Bioelectrocatalysis On the Nature of Microbial Bioelectrocatalysis Microbial Electron Transfer Mechanisms From Physiology to Technology: Microbial Bioelectrochemical Systems Applicatin Potential of BES Technology Characterization of BESs and Microbial Bioelectrocatalysts Conclusions MATERIALS FOR MICROFLUIDIC FUEL CELLS Introduction Fundamentals Membraneless LFFC Designs and the Materials in Use Fuel, Oxidant, and Electrolytes Conclusions PROGRESS IN ELECTROCATALYSTS FOR DIRECT ALCOHOL FUEL CELLS Introduction Developing an Effective Method to Prepare Electrocatalysts Electrocatalysts for ORR Electrocatalysts for MOR Electrocatalysts for Ethanol Electrooxidation Conclusions Index