Material Characteristics and Comparison of Silver Foil Glass Beads Excavated from the Tomb of King Muryeong in Korea

Abstract

This study investigated the comprehensive characteristics of silver foil beads excavated from the Tomb of King Muryeong, based on composition analysis of the foil and glass and morphological characterization. The major element components of metal foil and glass were investigated using a scanning electron microscope (SEM) equipped with an Energy Dispersive X-ray spectrometer (EDS). Trace elements were determined using LA-ICP-MS to constrain the source of the raw material. The morphological characteristics of the beads were recognized through an optical microscope. As a result of the analysis, the metal foil was detected as pure in both gold- and silver-colored glass beads. The chemical composition of the glass was determined as a soda glass, with Na+ acting as a flux and CaO added as a stabilizer to improve durability. It was confirmed that plant ash was used because MgO and K2O were found to contain more than 1.5%. Through trace element analysis, it was confirmed that the gold and silver-colored silver foil glass beads were made of plant ash glass using different materials. The content of Fe2O3 was significantly higher in the gold-colored silver foil glass beads than in the silver-colored silver foil glass beads. Therefore, it can be interpreted that the gold-colored silver foil glass beads excavated from the tomb of King Muryeong intentionally achieved the appearance of gold foil glass beads by controlling the color of the outer glass. The silver foil glass beads showed morphological differences according to the color of the outer glass. The gold-colored silver foil glass beads were manufactured as single or segment types, but the silver-colored silver foil glass beads were manufactured as segment types.