Abstract

The mechanical properties of components manufactured ("printed") by the Fused Filament Fabrication (FFF) process are usually limited by the cohesion achieved between melt-processed thermoplastic filament strands perpendicular to the filament deposition direction. This significantly limits the usefulness of the FFF process and commercial FFF printers for the production of a wide range of functional components and consumer goods, so that the FFF process is currently used for the production of prototypes for visualization purposes only. In order to open up potential markets for structural components in the future, the realization of an optimized bonding layer quality via a significantly improved cohesion between the filament strands is essential. Since the mechanical properties of polymeric materials generally depend on the density of molecular entanglements and tie molecules in the material structure, it is of the utmost importance to realize the highest possible density of such entanglements and tie molecules between the individual filament layers also in FFF components. The present work deals with different methods of heat input to improve the entanglement and tie molecule density in the bonding layer of FFF components through enhanced polymer diffusion at temperatures far above the glass transition temperature for amorphous plastics or the melting temperature for semi-crystalline plastics, respectively. Heat can be either globally or locally introduced by conduction, convection, and radiation, the latter being the most effective for the FFF process when applied locally via properly controlled laser radiation. Ideally, a compact, cost effective and easy to use radiation source is used for this purpose. Hence, a setup based on a diode laser is presented in this work. Furthermore, an idealized calculation of the amount of heat required to promote the formation of interfilament bonds and thus to achieve an increased mechanical property profile was carried out. Two types of materials commonly used for the FFF process, polylactic acid (PLA) and acrylic-butadiene-styrene copolymer (ABS), were used for the experimental procedure. After producing a special monofilament with improved laser absorption characteristics, test specimens were produced. As a reference, test specimens made of the same materials were printed with the conventional FFF process. The differently manufactured test specimens were characterized optically and visually, using a stereomicroscope, and mechanically, using tensile tests. In addition, specimens were produced with a specially designed device for local heat input onto the substrate layer region just ahead of the new filament deposition. The effectiveness of this laser-assisted method could be proven in tests by adjusting the process parameters of the FFF process. After finding the optimum printing speed (equivalent to the laser power applied) for the materials PLA and ABS, an optical examination of the fracture surfaces of test specimens with filaments laid down perpendicular to an applied tensile load showed a significant increase in plastic deformation capacity, indicative of an improved interfilament bonding. This was confirmed by the mechanical property values determined in tensile tests. Thus, for optimized printing speeds, an increase in tensile strength values of ~20% for PLA and ~7% for ABS was achieved. For elongation at break, the improvements were ~21% for PLA and ~34% for ABS, respectively. The methodology of laser-assisted FFF printing thus offers great potential for mechanically and structurally optimized functional components with specifically introduced anisotropy. • Interfilament entanglements control strength of printed polymer parts. • Novel diode laser-assisted fused filament fabrication process (FFF) is presented. • Enhanced local laser absorption and heat introduction via specific additives. • improved bonding layer strength of FFF components was achieved.

Highlights

  • The mechanical properties of components manufactured ("printed") by the Fused Filament Fabrication (FFF) process are usually limited by the cohesion achieved between melt-processed thermoplastic filament strands perpendicular to the filament deposition direction

  • The movement of the molecular chains and the subsequent formation of entanglements in the FFF pro­ cess is based on reptation [9,10,11] and depends on the surface tempera­ ture and the time the material is kept above the glass transition temperature for amorphous plastics or the melting temperature for semi-crystalline plastics [5,8,12,13,14]

  • A closed, heated chamber is limited by the heat deflection temperature (HDT) of the material being processed, i.e. at temperatures far below the temperatures required for effective interfilament bonds, since global exceeding of the HDT temperatures leads to instabilities of the entire part during manufacturing

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Summary

Introduction

The mechanical properties of components manufactured ("printed") by the Fused Filament Fabrication (FFF) process are usually limited by the cohesion achieved between melt-processed thermoplastic filament strands perpendicular to the filament deposition direction. After finding the optimum printing speed (equivalent to the laser power applied) for the materials PLA and ABS, an optical examination of the fracture surfaces of test specimens with filaments laid down perpendicular to an applied tensile load showed a significant increase in plastic deformation capacity, indicative of an improved interfilament bonding. This was confirmed by the mechanical property values determined in tensile tests. These include the heat output of the print head, the properties of the material used, as well as the filament diameter and volume flow [21,22,25,26]

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