Abstract

AbstractThe heat and mass transfer characteristics during the collision process of hydrocarbon droplets and polyethylene particles in a liquid‐containing gas–solid polyethylene fluidized bed reactor significantly affect the product quality. In this work, the mass transfer process of single‐component hydrocarbon and bi‐component hydrocarbon liquid films on the polyethylene particle surface were quantitatively characterized by a newly developed experimental approach, based on a novel synthesized hydrocarbon liquid soluble fluorescent probe for sensitive tracing of hydrocarbon liquid diffusion. It was found that the boiling point and surface tension of the liquid as well as the surface temperature of the particle are the key factors affecting the mass transfer properties of the liquid film. Marangoni convection was observed and characterized on the particle surface. The critical time for the onset of Marangoni flow is between 4 and 8 s.

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