Mass spectrometric studies of elusive molecules that contain an N(+)-X- bond.

Abstract

This review will be concerned with the gas phase chemistry of 1,2- and 1,3-dipolar systems that contain a carbon-nitrogen bond. Although most of these compounds are stable molecules under normal conditions, certain congeners are reactive species that cannot be prepared using conventional procedures. The isolation and observation of these elusive compounds therefore require appropriate experimental conditions such as those provided by the gas phase of a mass spectrometer. In these experiments, the radical cations, corresponding to the molecule under study, must be prepared via indirect procedures, including dissociative electron ionization, on-line flash-vacuum pyrolysis-mass spectrometry, or ion-molecule reactions. Their characterization is mainly based on collisional activation and ion-molecule reactions. The formation of the corresponding highly reactive neutrals is attempted by neutralization-reionization mass spectrometry. This review presents more than one hundred different molecules together with their methods of preparation and the experiment used to identify them.