Mass-composite activation energies for recycled binder blends

Abstract

Using reclaimed asphalt pavement (RAP) has become an appealing development for economic and environmental benefits. One of the key issues when incorporating RAP materials is to ensure the performance of recycled binder blends. Despite extensive researches dealing with physical and chemical aspects, concerns about recycled materials combinations remain. This paper focuses on the kinetics of aging, cracking and healing process for blended binders with a novel hypothesis of mass-composite activation energies. Firstly, four blends were prepared with different ratios of virgin bitumen and laboratory-produced RAP binders. Then, Fourier-transform infrared spectroscopy was utilized to track the carbonyl formation in all samples initially and with aging, and aging activation energy (Eacr) was computed in terms of Arrhenius equation. Thirdly, strain-controlled oscillatory measurements were conducted; moreover, representative energy change rates of dissipated pseudo strain energy and recoverable strain energy were obtained to determine the activation energy for cracking (Eac) and healing (EaH), respectively. Finally, hypotheses of mass-composite activation energies were validated with the test results. It shows that Eacr of recycled binder blends are smaller than that of RAP binders, indicating a lower kinetic barrier to oxidation reaction for blended bituminous system. With the increase of RAP binder content, the blends exhibit a decrease in Eac and an increase in EaH, which reveals the adverse effect introduced by oxidation in cracking resistance and healing capability. Excitingly, the measured activation energies of recycled binder blends are consistent with the calculated mass-composite activation energies, which will hopefully provide support for performance estimation.