Abstract
1H MAS NMR, 1H spin-echo MAS NMR with Al irradiation, 29Si MAS NMR, and 1H→ 29Si CP MAS NMR were used to investigate the deposition of Mo and Ni species on the surface of alumina and silica–alumina. Mo and Ni species first occupy the alumina sites and then the silica sites. The results of temperature-programmed reduction show that the weaker interaction between the Mo and Ni species and the silica–alumina support leads to better reducibility of the metal oxides on silica–alumina than on Al 2O 3. Mo and Ni species also interact with each other. Transmission electron microscopy proved that, after sulfidation, higher stacks of MoS 2 are formed on the silica–alumina support than on the Al 2O 3 support. The higher stacking is responsible for the higher hydrodenitrogenation activity of the NiMoS catalysts supported on silica–alumina.
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